Issue 30, 2014
From the journal:

Chemical Communications

A copper-catalyzed formal O–H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide†

Zikun Wang,a   Xihe Bi,b   Yongjiu Liang,*a   Peiqiu Liaob  and  Dewen Dong*a  

* Corresponding authors

a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: yjliang@ciac.ac.cn, dwdong@ciac.ac.cn

b Department of Chemistry, Northeast Normal University, Changchun, China

Abstract

A novel copper-catalyzed formal O–H insertion of α-diazo-1,3-dicarbonyl compounds to carboxylic acids has been developed, providing a straightforward synthetic method for α-acyloxy-1,3-dicarbonyl compounds, in which the activation of carboxylic acids by isocyanide plays a crucial role.

Graphical abstract: A copper-catalyzed formal O–H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide

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Article information

DOI
https://doi.org/10.1039/C4CC00402G
Article type
Communication
Submitted
17 Jan 2014
Accepted
24 Feb 2014
First published
24 Feb 2014

Chem. Commun., 2014,50, 3976-3978

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A copper-catalyzed formal O–H insertion reaction of α-diazo-1,3-dicarbonyl compounds to carboxylic acids with the assistance of isocyanide

Z. Wang, X. Bi, Y. Liang, P. Liao and D. Dong, Chem. Commun., 2014, 50, 3976 DOI: 10.1039/C4CC00402G

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