Issue 37, 2014
From the journal:

Chemical Communications

The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e− as an electron donor†

Ye Ji Kim,‡ab   Sun Min Kim,‡a   Hideo Hosono,c   Jung Woon Yang*a  and  Sung Wng Kim*ab  

* Corresponding authors

a Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Republic of Korea
E-mail: jwyang@skku.edu, kimsungwng@skku.edu
Fax: +82-31-299-4279
Tel: +82-31-299-4276

b IBS Center for Integrated Nanostructure Physics, Institute for Basic Science, Daejeon 305-701, Republic of Korea

c Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Abstract

The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e− as an electron donor in organic solvents. The bond cleavages of the [Ca2N]+ layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe)2 and ammonia.

Graphical abstract: The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e− as an electron donor

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Article information

DOI
https://doi.org/10.1039/C4CC00802B
Article type
Communication
Submitted
29 Jan 2014
Accepted
18 Mar 2014
First published
18 Mar 2014

Chem. Commun., 2014,50, 4791-4794

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The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N]+·e− as an electron donor

Y. J. Kim, S. M. Kim, H. Hosono, J. W. Yang and S. W. Kim, Chem. Commun., 2014, 50, 4791 DOI: 10.1039/C4CC00802B

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