Issue 43, 2014

Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

Abstract

A convenient and efficient phosphine-catalyzed sequential annulation domino reaction between dienic sulfones and MBH carbonates has been developed. In the presence of 20 mol% of tris(4-fluorophenyl)phosphine, functionalized bicyclo[4.1.0]heptenes were prepared in excellent yields and stereoselectivities under mild conditions.

Graphical abstract: Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

Supplementary files

Article information

Article type
Communication
Submitted
11 Feb 2014
Accepted
02 Apr 2014
First published
03 Apr 2014

Chem. Commun., 2014,50, 5710-5713

Phosphine-catalyzed sequential annulation domino reaction: rapid construction of bicyclo[4.1.0]heptene skeletons

J. Zheng, Y. Huang and Z. Li, Chem. Commun., 2014, 50, 5710 DOI: 10.1039/C4CC01097C

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