Alkyl substituted Hantzsch esters are rationally used as alkylation reagents to replace the nitro groups of nitro olefins to give excellent yields of trans-olefins. The reaction mechanism is considered to proceed through a free radical mechanism, which is different from the corresponding transfer alkylation of imines.
G. Li, L. Wu, G. Lv, H. Liu, Q. Fu, X. Zhang and Z. Tang, Chem. Commun., 2014, 50, 6246 DOI: 10.1039/C4CC01119H
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