Chemically regulating Rh(i)-Bodipy photoredox switches†
Abstract
The ability of Rh(I) centers to undergo photoinduced electron transfer from discrete metal orbitals to Bodipy fluorophores is mediated through reversible coordination chemistry.
* Corresponding authors
a
Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA
E-mail:
chadnano@northwestern.edu
b Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, Evanston, Illinois 60208, USA
The ability of Rh(I) centers to undergo photoinduced electron transfer from discrete metal orbitals to Bodipy fluorophores is mediated through reversible coordination chemistry.
A. M. Lifschitz, R. M. Young, J. Mendez-Arroyo, V. V. Roznyatovskiy, C. M. McGuirk, M. R. Wasielewski and C. A. Mirkin, Chem. Commun., 2014, 50, 6850 DOI: 10.1039/C4CC01345J
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