A BN substituted hexabenzotriphenylene (B3N3) closes one C–C-bond upon irradiation with light of 280–400 nm in the presence of iodine to yield a phenanthrene annelated B3N3 tribenzoperylene. Upon hydrolysis a B2N2 dibenzoperylene is obtained.
M. Müller, S. Behnle, C. Maichle-Mössmer and H. F. Bettinger, Chem. Commun., 2014, 50, 7821 DOI: 10.1039/C4CC01424C
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