Issue 53, 2014
From the journal:

Chemical Communications

On the hydrates of codeine phosphate: the remarkable influence of hydrogen bonding on the crystal size†

Tomče Runčevski,*a   Gjorgji Petruševski,b   Petre Makreski,c   Sonja Ugarkovicb  and  Robert E. Dinnebiera  

* Corresponding authors

a Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany
E-mail: t.runcevski@fkf.mpg.de

b Research & Development, ALKALOID AD, Aleksandar Makedonski 12, 1000 Skopje, Macedonia

c Institute of Chemistry, Faculty of Natural Sciences and Mathematics, SS. Cyril and Methodius University, Arhimedova 5, 1000 Skopje, Macedonia

Abstract

Codeine phosphate forms three hydrates and two anhydrates. The sesquihydrate and hemihydrate, which differ by one water molecule, are stable at room temperature. The influence of this molecule on the internal crystal structure and how it translates into the external crystal shape are reported.

Graphical abstract: On the hydrates of codeine phosphate: the remarkable influence of hydrogen bonding on the crystal size

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Article information

DOI
https://doi.org/10.1039/C4CC01430H
Article type
Communication
Submitted
24 Feb 2014
Accepted
28 Feb 2014
First published
06 Mar 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 6970-6972

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On the hydrates of codeine phosphate: the remarkable influence of hydrogen bonding on the crystal size

T. Runčevski, G. Petruševski, P. Makreski, S. Ugarkovic and R. E. Dinnebier, Chem. Commun., 2014, 50, 6970 DOI: 10.1039/C4CC01430H

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