Issue 44, 2014
From the journal:

Chemical Communications

Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion†

José Martínez-Lillo,*a   John Kong,a   Wdeson P. Barros,b   Juan Faus,b   Miguel Julveb  and  Euan K. Brechin*a  

* Corresponding authors

a EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: fmartine@staffmail.ed.ac.uk, ebrechin@staffmail.ed.ac.uk

b Instituto de Ciencia Molecular (ICMol), Universitat de Valéncia, C/ Catedrático José Beltrán 2, Paterna, Valéncia, Spain

Abstract

A new chloro-bridged heterobimetallic Cu(II)Re(IV) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (1·MeCN) has been prepared and magnetostructurally characterised. Compound 1 is the first example of the [ReIVCl6]2− anion acting as a metalloligand towards a paramagnetic metal ion.

Graphical abstract: Metamagnetic behaviour in a new Cu(ii)Re(iv) chain based on the hexachlororhenate(iv) anion

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Article information

DOI
https://doi.org/10.1039/C4CC01564A
Article type
Communication
Submitted
01 Mar 2014
Accepted
08 Apr 2014
First published
08 Apr 2014

Chem. Commun., 2014,50, 5840-5842

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Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

J. Martínez-Lillo, J. Kong, W. P. Barros, J. Faus, M. Julve and E. K. Brechin, Chem. Commun., 2014, 50, 5840 DOI: 10.1039/C4CC01564A

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