Issue 47, 2014
From the journal:

Chemical Communications

Catalytic [3 + 2] annulation of ketimines with alkynes via C–H activation by a cationic iridium(cod) complex†

Midori Nagamotoa  and  Takahiro Nishimura*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988
Tel: +81 75 753 3987

Abstract

[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded via C–H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).

Graphical abstract: Catalytic [3 + 2] annulation of ketimines with alkynes via C–H activation by a cationic iridium(cod) complex

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Article information

DOI
https://doi.org/10.1039/C4CC01874E
Article type
Communication
Submitted
13 Mar 2014
Accepted
16 Apr 2014
First published
23 Apr 2014

Chem. Commun., 2014,50, 6274-6277

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Catalytic [3 + 2] annulation of ketimines with alkynes via C–H activation by a cationic iridium(cod) complex

M. Nagamoto and T. Nishimura, Chem. Commun., 2014, 50, 6274 DOI: 10.1039/C4CC01874E

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