Issue 63, 2014
From the journal:

Chemical Communications

Water soluble octa-functionalized POSS: all-click chemistry synthesis and efficient host–guest encapsulation†

Jin Han,‡ab   Yaochen Zheng,‡ac   Shuai Zheng,‡a   Sipei Li,a   Tiannan Hu,a   Aijin Tanga  and  Chao Gao*a  

* Corresponding authors

a MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, P. R. China
E-mail: chaogao@zju.edu.cn

b Key Laboratory of Marine Materials and Related Technologies, Ningbo Institute of Materials Technology and Engineering (CAS), Ningbo 315201, P. R. China

c College of Chemistry and Chemical Engineering, Yantai University, 30 Qingquan Road, Yantai 264005, P. R. China

Abstract

A series of water soluble octa-functionalized POSSs were facilely synthesized via thiol–ene and Menschutkin click chemistry. Among them, octa-alkynyl POSS further reacted with azide-terminal alkyl long chains, resulting in a well-defined, amphiphilic octopus-like POSS. For the first time it was used for host–guest encapsulation and it exhibited an ultrahigh loading capability.

Graphical abstract: Water soluble octa-functionalized POSS: all-click chemistry synthesis and efficient host–guest encapsulation

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Article information

DOI
https://doi.org/10.1039/C4CC01956C
Article type
Communication
Submitted
16 Mar 2014
Accepted
15 May 2014
First published
19 May 2014

Chem. Commun., 2014,50, 8712-8714

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Water soluble octa-functionalized POSS: all-click chemistry synthesis and efficient host–guest encapsulation

J. Han, Y. Zheng, S. Zheng, S. Li, T. Hu, A. Tang and C. Gao, Chem. Commun., 2014, 50, 8712 DOI: 10.1039/C4CC01956C

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