A novel route to Δ2-isoxazolines is presented via silver-mediated radical cyclization of α-halo ketoximes with 1,3-dicarbonyl compounds. This method is performed using a radical strategy, and represents a new example of silver-initiated generation of oxime radicals for the formation of the C(sp3)–O bonds.
Y. Liu, X. Yang, J. Yang, R. Song and J. Li, Chem. Commun., 2014, 50, 6906 DOI: 10.1039/C4CC02084G
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