Issue 57, 2014

A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

Abstract

A layered erbium(III) phosphonate compound, [Er(notpH4)(H2O)]ClO4ยท3H2O (1), in which the ErIII ion has a pseudo-D5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.

Graphical abstract: A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

Supplementary files

Article information

Article type
Communication
Submitted
20 Mar 2014
Accepted
27 May 2014
First published
30 May 2014

Chem. Commun., 2014,50, 7621-7624

A layered erbium phosphonate in pseudo-D5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation

M. Ren, S. Bao, R. A. S. Ferreira, L. Zheng and L. D. Carlos, Chem. Commun., 2014, 50, 7621 DOI: 10.1039/C4CC02085E

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