Issue 57, 2014

Complex thermal expansion properties in a molecular honeycomb lattice

Abstract

[FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

Graphical abstract: Complex thermal expansion properties in a molecular honeycomb lattice

Supplementary files

Article information

Article type
Communication
Submitted
25 Mar 2014
Accepted
22 May 2014
First published
29 May 2014

Chem. Commun., 2014,50, 7601-7603

Complex thermal expansion properties in a molecular honeycomb lattice

J. J. Loughrey, T. P. Comyn, D. C. Apperley, M. A. Little and M. A. Halcrow, Chem. Commun., 2014, 50, 7601 DOI: 10.1039/C4CC02198C

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