A copper-catalysed direct oxidative Csp3–H methylenation to terminal olefins using DMF as one carbon source was developed. In this reaction, various functional groups were well tolerated, thus providing a simple way to construct arylvinylketones and arylvinylpyridines. The preliminary mechanistic investigations revealed that CH2 was from DMF (N–CH3).
J. Liu, H. Yi, X. Zhang, C. Liu, R. Liu, G. Zhang and A. Lei, Chem. Commun., 2014, 50, 7636 DOI: 10.1039/C4CC02275K
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