Issue 65, 2014

A spin-canted NiII4-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

Abstract

The reaction of nickel(II) nitrate with isonicotinic acid and 2,6-dimethyl-pyridine-3,5-dicarboxylic acid affords a novel, tetranuclear nickel(II)-based metal–organic framework that exhibits spin-canted antiferromagnetism with a canted angle of 1.65° and high adsorptive selectivity for light hydrocarbons.

Graphical abstract: A spin-canted NiII4-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

Supplementary files

Article information

Article type
Communication
Submitted
01 Apr 2014
Accepted
27 Jun 2014
First published
27 Jun 2014

Chem. Commun., 2014,50, 9161-9164

A spin-canted NiII4-based metal–organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons

J. Li, Y. Guo, H. Fu, J. Zhang, R. Huang, L. Zheng and J. Tao, Chem. Commun., 2014, 50, 9161 DOI: 10.1039/C4CC02396J

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