Issue 51, 2014
From the journal:

Chemical Communications

Development of a Ru complex-incorporated MOF photocatalyst for hydrogen production under visible-light irradiation†

Takashi Toyao,a   Masakazu Saito,a   Satoru Dohshi,b   Katsunori Mochizuki,c   Masatoshi Iwata,c   Hideyuki Higashimura,c   Yu Horiuchi*a  and  Masaya Matsuoka*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1, Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan
E-mail: horiuchi@chem.osakafu-u.ac.jp, matsumac@chem.osakafu-u.ac.jp
Fax: +81-072-254-9910
Tel: +81-072-254-9288

b Technology Research Institute of Osaka Prefecture, 1-18-13, Kishibe-naka, Suita, Osaka 564-0002, Japan

c Advanced Materials Research Laboratory, Sumitomo-Chemical Co., Ltd., 6, Kitahara, Tsukuba, Ibaraki 300-3294, Japan

Abstract

A Ru complex-incorporated Ti-based MOF (Ti-MOF-Ru(tpy)2) has been synthesised by using a bis(4′-(4-carboxyphenyl)-terpyridine)Ru(II) complex (Ru(tpy)2) as an organic linker. Ti-MOF-Ru(tpy)2 promotes photocatalytic hydrogen production from water containing a sacrificial electron donor under visible-light irradiation up to 620 nm.

Graphical abstract: Development of a Ru complex-incorporated MOF photocatalyst for hydrogen production under visible-light irradiation

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Article information

DOI
https://doi.org/10.1039/C4CC02397H
Article type
Communication
Submitted
01 Apr 2014
Accepted
30 Apr 2014
First published
01 May 2014

Chem. Commun., 2014,50, 6779-6781

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Development of a Ru complex-incorporated MOF photocatalyst for hydrogen production under visible-light irradiation

T. Toyao, M. Saito, S. Dohshi, K. Mochizuki, M. Iwata, H. Higashimura, Y. Horiuchi and M. Matsuoka, Chem. Commun., 2014, 50, 6779 DOI: 10.1039/C4CC02397H

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