T. Ikeda, R. Iino and H. Noji
Chem. Commun., 2014,50, 9443-9446
DOI:
10.1039/C4CC02574A,
Communication
The emission transition dipole moments of single-molecule free-base phthalocyanines at an air/glass interface were visualized using defocused wide-field fluorescence microscopy at a temporal resolution of 100–200 ms. Isolated molecules showed slow proton tautomerization, which is consistent with previous theoretical calculations in the gas phase, which predicted large activation energies.