Three related aromatic [22] heteroporphyrins have been synthesized and characterized, with the target of achieving NIR absorption. The propensity of these smallest π-conjugated macrocycles to absorb in the NIR region is benefitted from the fusion/annelation of the precursor heterocycles.
![Graphical abstract: Aromatic fused heterocyclic [22] macrocycles with NIR absorption](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC02749C&imageInfo.ImageIdentifier.Year=2014)
H. Rath, A. Mallick, T. Ghosh and A. Kalita, Chem. Commun., 2014, 50, 9094 DOI: 10.1039/C4CC02749C
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