The preparation under protic conditions of the first μ-hydroxo dicopper(I)–NHC complex is reported. Its application as a CuAAC catalyst was investigated, evidencing a remarkable enhancement of catalytic efficiency in the presence of 4,7-dichloro-1,10-phenanthroline and highlighting the beneficial effect of the absence of coordinating halides.
![Graphical abstract: [{Cu(IPr)}2(μ-OH)][BF4]: synthesis and halide-free CuAAC catalysis](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC03346A&imageInfo.ImageIdentifier.Year=2014)
H. Ibrahim, R. Guillot, F. Cisnetti and A. Gautier, Chem. Commun., 2014, 50, 7154 DOI: 10.1039/C4CC03346A
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