Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

Mirim Kim; Satyasheel Sharma; Neeraj Kumar Mishra; Sangil Han; Jihye Park; Minyoung Kim; Youngmi Shin; Jong Hwan Kwak; Sang Hoon Han; In Su Kim

doi:10.1039/C4CC03354J

Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis†

Mirim Kim,^a Satyasheel Sharma,^a Neeraj Kumar Mishra,^a Sangil Han,^a Jihye Park,^a Minyoung Kim,^a Youngmi Shin,^a Jong Hwan Kwak,^a Sang Hoon Han^a and In Su Kim*^a

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^a School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea
E-mail: insukim@skku.edu
Fax: +82 31 292 8800
Tel: +82 31 290 7788

Abstract

The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates.

Chemical Communications

Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis†

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Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

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