The first example of a dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of catalytic amounts of Selectfluor and DABCO was reported, which provides a facile access to organoboronates. This reaction represents an unprecedented dyotropic rearrangement consisting of cleavage of two vicinal bonds (one C–C bond and one C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C bond).
W. Ye, W. Li and J. Zhang, Chem. Commun., 2014, 50, 9879 DOI: 10.1039/C4CC03450C
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