AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

Minsik Min; Donghee Kim; Sungwoo Hong

doi:10.1039/C4CC03602F

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AgSbF₆-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes†

Minsik Min,^a Donghee Kim^a and Sungwoo Hong*^a

Author affiliations

* Corresponding authors

^a Center for Catalytic Hydrocarbon Functionalizations, Institute of Basic Science (IBS) and Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon, Korea
E-mail: hongorg@kaist.ac.kr
Fax: +82 42-350-2810
Tel: +82 42-350-2811

Abstract

AgSbF₆-controlled diastereodivergent hydroarylation reactions were developed. Unprecedented and remarkable switching of the E/Z-stereoselectivity could be obtained by adjusting the AgSbF₆ loading.

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Article information

DOI: https://doi.org/10.1039/C4CC03602F
Article type: Communication
Submitted: 13 May 2014
Accepted: 03 Jun 2014
First published: 04 Jun 2014

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Chem. Commun., 2014,50, 8028-8031

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AgSbF₆-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

M. Min, D. Kim and S. Hong, Chem. Commun., 2014, 50, 8028 DOI: 10.1039/C4CC03602F

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