Issue 70, 2014
From the journal:

Chemical Communications

A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties†

Bart Bueken,a   Helge Reinsch,a   Nele Reimer,b   Ivo Stassen,a   Frederik Vermoortele,a   Rob Ameloot,a   Norbert Stock,b   Christine E. A. Kirschhocka  and  Dirk De Vos*a  

* Corresponding authors

a Centre for Surface Chemistry and Catalysis, KU Leuven – University of Leuven, Kasteelpark Arenberg 23 post box 2461, 3001 Leuven, Belgium
E-mail: dirk.devos@biw.kuleuven.be

b Institut für Anorganische Chemie, Christian-Albrechts-Unversität, Max-Eyth Straße 2, D 24118 Kiel, Germany

Abstract

We report the first zirconium metal–organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.

Graphical abstract: A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

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Article information

DOI
https://doi.org/10.1039/C4CC03764B
Article type
Communication
Submitted
16 May 2014
Accepted
11 Jul 2014
First published
11 Jul 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 10055-10058

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A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

B. Bueken, H. Reinsch, N. Reimer, I. Stassen, F. Vermoortele, R. Ameloot, N. Stock, C. E. A. Kirschhock and D. De Vos, Chem. Commun., 2014, 50, 10055 DOI: 10.1039/C4CC03764B

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