A new polyoxomolybdate-based hybrid platform TBA4[PMo11O39{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.
C. Rinfray, S. Renaudineau, G. Izzet and A. Proust, Chem. Commun., 2014, 50, 8575 DOI: 10.1039/C4CC03779K
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