Issue 69, 2014
From the journal:

Chemical Communications

Direct oxidative nitration of aromatic sulfonamides under mild conditions†

Ying-Xiu Li,a   Lian-Hua Li,a   Yan-Fang Yang,a   Hui-Liang Hua,a   Xiao-Biao Yan,a   Lian-Biao Zhao,b   Jin-Bang Zhang,a   Fa-Jin Jic  and  Yong-Min Liang*a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
E-mail: liangym@lzu.edu.cn
Fax: +86-931-8912582
Tel: +86-931-8912582

b College of Chemical Engineering, Northwest University for Nationalities, Lanzhou 730030, China

c The Eighth Middle School, Yong jing 731605, China

Abstract

A direct nitration of aromatic sulfonamides using sodium nitrite as the nitrating agent has been developed. The reaction shows typically mono-substitution selectivity and can be enlarged to the gram scale with good yield.

Graphical abstract: Direct oxidative nitration of aromatic sulfonamides under mild conditions

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Article information

DOI
https://doi.org/10.1039/C4CC03784G
Article type
Communication
Submitted
18 May 2014
Accepted
09 Jul 2014
First published
09 Jul 2014

Chem. Commun., 2014,50, 9936-9938

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Direct oxidative nitration of aromatic sulfonamides under mild conditions

Y. Li, L. Li, Y. Yang, H. Hua, X. Yan, L. Zhao, J. Zhang, F. Ji and Y. Liang, Chem. Commun., 2014, 50, 9936 DOI: 10.1039/C4CC03784G

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