Issue 82, 2014
From the journal:

Chemical Communications

Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes†

Mujahuddin M. Siddiqui,a   Shaikh M. Mobin,b   Irena Senkovska,c   Stefan Kaskelc  and  Maravanji S. Balakrishna*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India
E-mail: krishna@chem.iitb.ac.in

b Discipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Indore 452017, India

c Department of Inorganic Chemistry, Technische Universität Dresden, Bergstr. 66, 01062 Dresden, Germany

Abstract

Two novel cyclodiphosphazane cluster frameworks with Cu4X4 clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η5-C5H4)2(PNtBu)2] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.

Graphical abstract: Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes

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Article information

DOI
https://doi.org/10.1039/C4CC03810J
Article type
Communication
Submitted
19 May 2014
Accepted
23 Jun 2014
First published
23 Jun 2014

Chem. Commun., 2014,50, 12273-12276

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Novel zeotype frameworks with soft cyclodiphosphazane linkers and soft Cu4X4 clusters as nodes

M. M. Siddiqui, S. M. Mobin, I. Senkovska, S. Kaskel and M. S. Balakrishna, Chem. Commun., 2014, 50, 12273 DOI: 10.1039/C4CC03810J

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