Different enamines were introduced at the meso position of the BODIPY by catalyst free oxidation of tert-amines and in situ cross coupling with 8-chloro BODIPY. The reaction conditions were optimized to achieve better yields. The reaction works well with aliphatic tert-amines bearing an N-(CH–CH–) backbone. The N-alkyl substituents perturb the optical properties of enamine substituted BODIPYs.
B. Dhokale, T. Jadhav, S. M. Mobin and R. Misra, Chem. Commun., 2014, 50, 9119 DOI: 10.1039/C4CC03857F
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