Reaction of d0 Zr(NMe2)2[MeC(NiPr)2]2 (1) with O2 at −30 °C gives three Zr containing products: a peroxo trimer {(μ-η2:η2-O2)Zr[MeC(NiPr)2]2}3 (2), an oxo dimer {(μ-O)Zr[MeC(NiPr)2]2}2 (3), and an oxo polymer {(μ-O)Zr[MeC(NiPr)2]2}n (4). 2 is a rarely observed peroxo complex from the reaction of a d0 complex with O2.
A. C. Lamb, Z. Lu and Z. Xue, Chem. Commun., 2014, 50, 10517 DOI: 10.1039/C4CC04032E
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