Issue 69, 2014
From the journal:

Chemical Communications

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature†

Chao Feng,‡a   Daming Feng‡a  and  Teck-Peng Loh*ab  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
E-mail: teckpeng@ntu.edu.sg

b Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, P. R. China

Abstract

Rh(III)-catalyzed C–H olefinic alkynylation of enamides for the stereospecific construction of synthetically useful Z-type enynamides is reported. This protocol displays good functionality tolerance and operational simplicity thus providing an alternative synthetic opportunity for the ease of access to specific 1,3-enyne derivatives.

Graphical abstract: Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

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Article information

DOI
https://doi.org/10.1039/C4CC04072D
Article type
Communication
Submitted
28 May 2014
Accepted
03 Jul 2014
First published
03 Jul 2014

Chem. Commun., 2014,50, 9865-9868

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Rhodium(III)-catalyzed olefinic C–H alkynylation of enamides at room temperature

C. Feng, D. Feng and T. Loh, Chem. Commun., 2014, 50, 9865 DOI: 10.1039/C4CC04072D

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