Issue 84, 2014
From the journal:

Chemical Communications

An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex†

Yongdong Liu,a   Rui Xiang,a   Xiaoqiang Du,a   Yong Ding*ab  and  Baochun Ma*a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
E-mail: dingyong1@lzu.edu.cn, mabaochun@lzu.edu.cn

b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Abstract

A family of oxygen evolving catalysts was investigated, which was based on the most desired first-row transition metal iron. Among them, the highest turnover number of 2380 was obtained in acetate buffer at pH 4.5 with [(TPA)2Fe2(μ-O)(μ-OAc)]3+.

Graphical abstract: An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex

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Article information

DOI
https://doi.org/10.1039/C4CC04118F
Article type
Communication
Submitted
29 May 2014
Accepted
29 Aug 2014
First published
02 Sep 2014

Chem. Commun., 2014,50, 12779-12782

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An efficient oxygen evolving catalyst based on a μ-O diiron coordination complex

Y. Liu, R. Xiang, X. Du, Y. Ding and B. Ma, Chem. Commun., 2014, 50, 12779 DOI: 10.1039/C4CC04118F

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