We report [Y{N(SiMe3)2}3] as a precatalyst for the dehydrocoupling of sterically demanding amines with β-diketiminate stabilised aluminium dihydrides. While simple fluorinated anilines readily undergo Al–H/N–H dehydrocoupling under thermal conditions, catalytic methods are required to achieve reasonable rates of reaction for ortho-substituted anilines or hindered aliphatic amines.
A. E. Nako, S. J. Gates, N. Schädel, A. J. P. White and M. R. Crimmin, Chem. Commun., 2014, 50, 9536 DOI: 10.1039/C4CC04484C
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