Metal-free sp3 C–H functionalization: a novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

Satpal Singh Badsara; Yi-Chen Liu; Ping-An Hsieh; Jing-Wen Zeng; Shao-Yi Lu; Yi-Wei Liu; Chin-Fa Lee

doi:10.1039/C4CC04503C

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Metal-free sp³ C–H functionalization: a novel approach for the syntheses of selenide ethers and thioesters from methyl arenes†

Satpal Singh Badsara,^a Yi-Chen Liu,^a Ping-An Hsieh,^a Jing-Wen Zeng,^a Shao-Yi Lu,^a Yi-Wei Liu^a and Chin-Fa Lee*^a

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* Corresponding authors

^a Department of Chemistry, National Chung Hsing University, Taichung, Taiwan 402, Republic of China
E-mail: cfalee@dragon.nchu.edu.tw
Fax: +886 4 2286 2547
Tel: +886 4 2284 0411 ext. 810

Abstract

A DTBP-promoted metal-free and solvent-free formation of C–Se and C–S bonds through sp³ C–H functionalization of methyl arenes with diselenides and disulfides is described.

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Article information

DOI: https://doi.org/10.1039/C4CC04503C
Article type: Communication
Submitted: 13 Jun 2014
Accepted: 29 Jul 2014
First published: 01 Aug 2014

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Chem. Commun., 2014,50, 11374-11377

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Metal-free sp³ C–H functionalization: a novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

S. S. Badsara, Y. Liu, P. Hsieh, J. Zeng, S. Lu, Y. Liu and C. Lee, Chem. Commun., 2014, 50, 11374 DOI: 10.1039/C4CC04503C

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