Issue 76, 2014
From the journal:

Chemical Communications

Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines†

Shuanglong Lu,a   Chao Li,a   Jiaqing Wang,a   Yue Pan,a   Xueqing Caoa  and  Hongwei Gu*a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, China
E-mail: hongwei@suda.edu.cn
Fax: +86-65880905
Tel: +86-65880905

Abstract

A novel one-pot method has been developed for the interfacial hydrogenation of nitriles to synthesize asymmetrical tertiary amines. The active Pt NWs allow for the preparation of a series of tertiary amines in excellent yields (up to 99.0%) and a mixed solvent is vital for the adjustment of the yield. And also, the reaction proceeded under mild conditions and is environmentally friendly.

Graphical abstract: Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

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Article information

DOI
https://doi.org/10.1039/C4CC05132G
Article type
Communication
Submitted
04 Jul 2014
Accepted
30 Jul 2014
First published
30 Jul 2014

Chem. Commun., 2014,50, 11110-11113

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Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines

S. Lu, C. Li, J. Wang, Y. Pan, X. Cao and H. Gu, Chem. Commun., 2014, 50, 11110 DOI: 10.1039/C4CC05132G

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