Issue 91, 2014
From the journal:

Chemical Communications

Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate†

Xiaohu Hong,a   Hao Wang,a   Bingxin Liua  and  Bin Xu*abc  

* Corresponding authors

a School of Materials Science and Engineering, Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China
E-mail: xubin@shu.edu.cn
Fax: +86-21-66132830
Tel: +86-21-66132830

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

c Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China

Abstract

An efficient ruthenium-catalyzed double-fold C–H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products.

Graphical abstract: Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

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Article information

DOI
https://doi.org/10.1039/C4CC05173D
Article type
Communication
Submitted
05 Jul 2014
Accepted
12 Sep 2014
First published
17 Sep 2014

Chem. Commun., 2014,50, 14129-14132

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Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

X. Hong, H. Wang, B. Liu and B. Xu, Chem. Commun., 2014, 50, 14129 DOI: 10.1039/C4CC05173D

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