Li-rich anti-perovskite Li3OCl films with enhanced ionic conductivity

Xujie Lü; Gang Wu; John W. Howard; Aiping Chen; Yusheng Zhao; Luke L. Daemen; Quanxi Jia

doi:10.1039/C4CC05372A

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Li-rich anti-perovskite Li₃OCl films with enhanced ionic conductivity†

Xujie Lü,*^ab Gang Wu,^a John W. Howard,^ab Aiping Chen,^a Yusheng Zhao,*^b Luke L. Daemen^a and Quanxi Jia*^a

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* Corresponding authors

^a Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: xujie@lanl.gov, qxjia@lanl.gov
Fax: +1-(505) 665-9030
Tel: +1-(505) 665-9399

^b University of Nevada, Las Vegas, Nevada 89154, USA
E-mail: yusheng.zhao@unlv.edu

Abstract

Anti-perovskite solid electrolyte films were prepared by pulsed laser deposition, and their room-temperature ionic conductivity can be improved by more than an order of magnitude in comparison with its bulk counterpart. The cyclability of Li₃OCl films in contact with lithium was evaluated using a Li/Li₃OCl/Li symmetric cell, showing self-stabilization during cycling test.

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Article information

DOI: https://doi.org/10.1039/C4CC05372A
Article type: Communication
Submitted: 11 Jul 2014
Accepted: 13 Aug 2014
First published: 13 Aug 2014

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Chem. Commun., 2014,50, 11520-11522

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Li-rich anti-perovskite Li₃OCl films with enhanced ionic conductivity

X. Lü, G. Wu, J. W. Howard, A. Chen, Y. Zhao, L. L. Daemen and Q. Jia, Chem. Commun., 2014, 50, 11520 DOI: 10.1039/C4CC05372A

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