A Li3N protection layer is fabricated on the surface of a Li anode by an in situ method to suppress the shuttle effect on the basis of anode protection. The discharge capacity is retained at 773 mA h g−1 after 500 cycles with an average coulombic efficiency of 92.3% in the electrolyte without LiNO3, while the sulfur loading of the simple sulfur cathode was 2.5–3 mg cm−2.
G. Ma, Z. Wen, M. Wu, C. Shen, Q. Wang, J. Jin and X. Wu, Chem. Commun., 2014, 50, 14209 DOI: 10.1039/C4CC05535G
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