Herein, we first report a novel approach for preparing 3D π–π stacked crystals of polyaniline and polypyrrole and show how they self-assemble in a suitable solution environment. 3D crystals of polyaniline and polypyrrole show high charge-transport properties of 130 S cm−1 and 150 S cm−1, respectively. Remarkably, the 3D crystals of polyaniline obtain excellent anisotropic conductivity.
Y. Tao, J. Li, A. Xie, S. Li, P. Chen, L. Ni and Y. Shen, Chem. Commun., 2014, 50, 12757 DOI: 10.1039/C4CC05559D
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