The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.
J. A. Souto, W. Lewis and R. A. Stockman, Chem. Commun., 2014, 50, 12630 DOI: 10.1039/C4CC05751A
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