A potential-controlled two-step bidirectional communication protocol between the nanoswitches [Cu(1)]+, 2 and 3 is set up, in which ligand followed by metal-ion oxidation drives two subsequent metal ion translocations (self-sorting) changing the switching state at each switch. The communication is reset to its starting point by a two-electron reduction.
S. Pramanik, S. De and M. Schmittel, Chem. Commun., 2014, 50, 13254 DOI: 10.1039/C4CC05773B
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