We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.
M. B. Geeson, A. R. Jupp, J. E. McGrady and J. M. Goicoechea, Chem. Commun., 2014, 50, 12281 DOI: 10.1039/C4CC06094F
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