Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc3N@Ih-C80 affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes

Bin Liu; Hailin Cong; Xiaofang Li; Bing Yu; Lipiao Bao; Wenting Cai; Yunpeng Xie; Xing Lu

doi:10.1039/C4CC06134A

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Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc₃N@I_h-C₈₀ affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes†

Bin Liu,‡^a Hailin Cong,‡^b Xiaofang Li,*^a Bing Yu,^b Lipiao Bao,^c Wenting Cai,^c Yunpeng Xie^c and Xing Lu*^c

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* Corresponding authors

^a Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
E-mail: lixiaofang@iccas.ac.cn

^b Lab for New Fiber Materials and Modern Textile-Growing Base for State Key Laboratory, College of Chemical and Environmental Engineering, Qingdao University, Qingdao, China

^c State Key Laboratory of Materials Processing and Die & Mold Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China
E-mail: lux@hust.edu.cn

Abstract

Formation of a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes was achieved by the first 1,3-dipolar cycloaddition reaction of Sc₃N@C₈₀ with diphenylnitrilimine in a highly regioselective manner.

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Article information

DOI: https://doi.org/10.1039/C4CC06134A
Article type: Communication
Submitted: 06 Aug 2014
Accepted: 01 Sep 2014
First published: 01 Sep 2014

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Chem. Commun., 2014,50, 12710-12713

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Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc₃N@I_h-C₈₀ affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes

B. Liu, H. Cong, X. Li, B. Yu, L. Bao, W. Cai, Y. Xie and X. Lu, Chem. Commun., 2014, 50, 12710 DOI: 10.1039/C4CC06134A

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Chemical Communications