Issue 87, 2014
From the journal:

Chemical Communications

Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane†‡

Nicole Harmgarth,a   Cristian G. Hrib,a   Volker Lorenz,a   Liane Hilferta  and  Frank T. Edelmann*a  

* Corresponding authors

a Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, D-39106 Magdeburg, Germany
E-mail: frank.edelmann@ovgu.de
Fax: +49-391-6712933

Abstract

An unprecedented deboronation reaction of icosahedral carboranes is described, in which a BH group of m-carborane is detached from the cage and incorporated into an unusual nido-carborane-anellated diazadiborepine ring system.

Graphical abstract: Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

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Article information

DOI
https://doi.org/10.1039/C4CC06261B
Article type
Communication
Submitted
16 Aug 2014
Accepted
10 Sep 2014
First published
10 Sep 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 13239-13242

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Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

N. Harmgarth, C. G. Hrib, V. Lorenz, L. Hilfert and F. T. Edelmann, Chem. Commun., 2014, 50, 13239 DOI: 10.1039/C4CC06261B

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