The synthesis of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based polymers using a Pd-catalyzed oxidative C–H/C–H homopolymerization reaction

Qiang Zhang; Xiangjian Wan; Yan Lu; Yandong Li; Yuefeng Li; Chenxi Li; Hao Wu; Yongsheng Chen

doi:10.1039/C4CC06284A

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The synthesis of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based polymers using a Pd-catalyzed oxidative C–H/C–H homopolymerization reaction†

Qiang Zhang,^a Xiangjian Wan,^a Yan Lu,

*^b Yandong Li,^a Yuefeng Li,^a Chenxi Li,*^a Hao Wu^a and Yongsheng Chen*^a

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* Corresponding authors

^a Key Laboratory of Functional Polymer Materials, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Center for Nanoscale Science and Technology, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin, China
E-mail: yschen99@nankai.edu.cn, lichenxi@nankai.edu.cn

^b School of Materials Science & Engineering, Tianjin University of Technology, Tianjin, China
E-mail: luyan@tjut.edu.cn

Abstract

A new, simple, mild, atom economical homopolymerization method through Pd-catalyzed oxidative C–H/C–H coupling was developed for the preparation of a series of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based conjugated polymers.

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Article information

DOI: https://doi.org/10.1039/C4CC06284A
Article type: Communication
Submitted: 11 Aug 2014
Accepted: 28 Aug 2014
First published: 28 Aug 2014

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Chem. Commun., 2014,50, 12497-12499

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The synthesis of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based polymers using a Pd-catalyzed oxidative C–H/C–H homopolymerization reaction

Q. Zhang, X. Wan, Y. Lu, Y. Li, Y. Li, C. Li, H. Wu and Y. Chen, Chem. Commun., 2014, 50, 12497 DOI: 10.1039/C4CC06284A

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Chemical Communications

The synthesis of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based polymers using a Pd-catalyzed oxidative C–H/C–H homopolymerization reaction†

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The synthesis of 5-alkyl[3,4-c]thienopyrrole-4,6-dione-based polymers using a Pd-catalyzed oxidative C–H/C–H homopolymerization reaction

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