A stable nickel(II) methyl complex containing a diphosphino-boryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni–Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a σ-B–H Ni(0) species that further undergoes B–H oxidative addition to form a Ni(II) hydride complex.
N. Curado, C. Maya, J. López-Serrano and A. Rodríguez, Chem. Commun., 2014, 50, 15718 DOI: 10.1039/C4CC07616H
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