Issue 95, 2014
From the journal:

Chemical Communications

Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation†

Jinqiao Dong,a   Yan Liu*a  and  Yong Cui*ab  

* Corresponding authors

a School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: yongcui@sjtu.edu.cn, liuy@sjtu.edu.cn
Fax: +86 21-5474-1297

b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Abstract

Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF-1 is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.

Graphical abstract: Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

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Article information

DOI
https://doi.org/10.1039/C4CC07648F
Article type
Communication
Submitted
28 Sep 2014
Accepted
13 Oct 2014
First published
13 Oct 2014

Chem. Commun., 2014,50, 14949-14952

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Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

J. Dong, Y. Liu and Y. Cui, Chem. Commun., 2014, 50, 14949 DOI: 10.1039/C4CC07648F

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