Issue 99, 2014
From the journal:

Chemical Communications

A highly luminescent and highly oxygen-sensitive Tb(iii) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand†

Hidetaka Nakai,*ab   Takahiro Goto,a   Kazuhiro Kitagawa,ac   Kyoshiro Nonaka,ac   Takahiro Matsumotoabc  and  Seiji Ogo*abc  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: nakai@mail.cstm.kyushu-u.ac.jp
Fax: +81-92-802-2823
Tel: +81-92-802-2822

b Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

c International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

This communication presents a new terbium(III) complex that shows the highest luminescence quantum yield among the oxygen-sensitive lanthanide complexes (Φ = 0.91 under N2, Φ = 0.054 under air).

Graphical abstract: A highly luminescent and highly oxygen-sensitive Tb(iii) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

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Article information

DOI
https://doi.org/10.1039/C4CC07717B
Article type
Communication
Submitted
30 Sep 2014
Accepted
27 Oct 2014
First published
27 Oct 2014

Chem. Commun., 2014,50, 15737-15739

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A highly luminescent and highly oxygen-sensitive Tb(III) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

H. Nakai, T. Goto, K. Kitagawa, K. Nonaka, T. Matsumoto and S. Ogo, Chem. Commun., 2014, 50, 15737 DOI: 10.1039/C4CC07717B

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