A unique microporous copper trimesate selenite with high selectivity for CO2

Giannis S. Papaefstathiou; Kota S. Subrahmanyam; Gerasimos S. Armatas; Christos D. Malliakas; Mercouri G. Kanatzidis; Manolis J. Manos

doi:10.1039/C4CE00091A

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A unique microporous copper trimesate selenite with high selectivity for CO₂†

Giannis S. Papaefstathiou,^a Kota S. Subrahmanyam,^b Gerasimos S. Armatas,^c Christos D. Malliakas,^b Mercouri G. Kanatzidis^b and Manolis J. Manos*^d

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* Corresponding authors

^a Laboratory of Inorganic Chemistry, Chemistry Department, National and Kapodistrian University of Athens, 15771 Zografou, Greece

^b Chemistry Department, Northwestern University, Evanston, IL 60208, USA

^c Department of Materials Science and Technology, University of Crete, 71003 Heraklion, Greece

^d Chemistry Department, University of Ioannina, 45110 Ioannina, Greece
E-mail: emanos@cc.uoi.gr

Abstract

A copper trimesate selenite compound is reported which shows a robust 3-D porous structure with unprecedented structural characteristics and represents a unique example of a metal inorganic–organic framework with considerable permanent microporosity and selective CO₂ sorption properties.

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DOI: https://doi.org/10.1039/C4CE00091A
Article type: Communication
Submitted: 14 Jan 2014
Accepted: 14 Feb 2014
First published: 14 Feb 2014

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CrystEngComm, 2014,16, 3483-3486

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A unique microporous copper trimesate selenite with high selectivity for CO₂

G. S. Papaefstathiou, K. S. Subrahmanyam, G. S. Armatas, C. D. Malliakas, M. G. Kanatzidis and M. J. Manos, CrystEngComm, 2014, 16, 3483 DOI: 10.1039/C4CE00091A

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