Assembly of a calix[4]arene-supported MnIIIMnII cluster mediated by halogen interactions

Stephanie M. Taylor; Jamie M. Frost; Ross McLellan; Ruaraidh D. McIntosh; Euan K. Brechin; Scott J. Dalgarno

doi:10.1039/C4CE00729H

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Assembly of a calix[4]arene-supported Mn^IIIMn^II cluster mediated by halogen interactions†

Stephanie M. Taylor,^a Jamie M. Frost,^a Ross McLellan,^b Ruaraidh D. McIntosh,^b Euan K. Brechin*^a and Scott J. Dalgarno*^b

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

^b Institute of Chemical Sciences, Heriot – Watt University, Riccarton, Edinburgh, Scotland, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44 (0)131 451 3180
Tel: +44 (0)131 451 8025

Abstract

A new calix[4]arene-supported Mn^IIIMn^II cluster, formed by the introduction of 3,5-dichlorobenzoate to a system known to afford Mn^III₂Mn^II₂ Single-Molecule Magnets (SMMs), assembles in a layered manner through halogen interactions; structural and magnetic properties of this new cluster are presented.

This article is part of the themed collection: International Year of Crystallography Celebration: Europe and South Africa

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Article information

DOI: https://doi.org/10.1039/C4CE00729H
Article type: Communication
Submitted: 07 Apr 2014
Accepted: 11 Jun 2014
First published: 26 Jun 2014
This article is Open Access

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CrystEngComm, 2014,16, 8098-8101

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Assembly of a calix[4]arene-supported Mn^IIIMn^II cluster mediated by halogen interactions

S. M. Taylor, J. M. Frost, R. McLellan, R. D. McIntosh, E. K. Brechin and S. J. Dalgarno, CrystEngComm, 2014, 16, 8098 DOI: 10.1039/C4CE00729H

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