Facile synthesis of Ag–ZnO hybrid nanospindles for highly efficient photocatalytic degradation of methyl orange

Abstract

Highly photocatalytically active Ag nanoparticle decorated ZnO nanospindles were synthesized by a facile wet chemical method. The structural and optical properties of the as-synthesized materials were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and high resolution TEM (HRTEM) with energy dispersive X-ray spectroscopy, UV-visible absorption spectroscopy and Raman spectroscopy. The photocatalytic activity of these nanostructures was evaluated by analyzing sunlight driven degradation of methyl orange (MO) dye and it was observed that Ag nanoparticle modified ZnO nanospindles show significantly enhanced photocatalytic activity for degradation of MO, as compared to ZnO nanospindles. We attribute the observed enhanced photocatalytic activity of Ag nanoparticle decorated ZnO nanospindles to their improved sunlight utilization efficiency and the efficient suppression of recombination of photogenerated charge carriers due to the electron scavenging action of Ag nanoparticles and the interfacial electron transfers due to the Schottky junction between Ag nanoparticles and ZnO nanospindles.