Issue 4, 2014
From the journal:

Dalton Transactions

Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(iv) starting materials†

Sean D. Reilly,a   Jessie L. Brown,a   Brian L. Scottb  and  Andrew J. Gaunt*a  

* Corresponding authors

a Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
E-mail: gaunt@lanl.gov
Tel: +1 505 667 3395

b Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

The 1,2-dimethoxyethane (DME) solvento adducts of Np(IV) and Pu(IV) tetrachloride have been prepared and isolated in good and moderate yields, respectively, along with single-crystal structural determinations. These neutral molecules are expected to provide alternative synthetic pathways in the pursuit of non-aqueous and organometallic complexes.

Graphical abstract: Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(iv) starting materials

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT53058B
Article type
Communication
Submitted
29 Oct 2013
Accepted
19 Nov 2013
First published
27 Nov 2013

Dalton Trans., 2014,43, 1498-1501

Permissions

Request permissions

Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(IV) starting materials

S. D. Reilly, J. L. Brown, B. L. Scott and A. J. Gaunt, Dalton Trans., 2014, 43, 1498 DOI: 10.1039/C3DT53058B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements